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Two novel fomannosane-type sesquiterpenoids from the culture of the basidiomycete Agrocybe salicacola |
Liang-Yan LIUa,b, Zheng-Hui LIa, Ze-Jun DONGa, Xing-Yao LIa,b, Jia SUa,b, Yan LIa, Ji-Kai LIUa |
a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, China; b Graduate University of Chinese Academy of Sciences, Beijing 100049, Chin |
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Abstract Two novel fomannosane-type sesquiterpenoids, agrocybins H(1) and I(2), together with a known compound illudosin(3), were isolated from the culture broth of the mushroom Agrocybe salicacola. Their structures were elucidated by extensive spectroscopic analysis. The relative stereochemistry of 1 was determined by the use of single crystal X-ray crystallographic diffraction.
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Keywords
Agrocybe salicacola
fomannosane-type sesquiterpenoids
agrocybins
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Fund:This project was supported by the National Basic Research Program of China(973 Program, 2009CB522300), and the National Natural Sciences Foundation of China(30830113, U1132607). |
Issue Date: 11 February 2018
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