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Guajadials C-F, four unusual meroterpenoids from Psidium guajava |
Yuan GAOa,b,c, Gen-Tao LIa, Yan LIa, Ping HAIb, Fei WANGa,b, Ji-Kai LIUa |
a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, China; b BioBioPha Co., Ltd., Kunming 650201, China; c University of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract Guajadials C-F (1-4), four sesquiterpenoid-based meroterpenoids with unprecedented skeletons were isolated from the leaves of Psidium guajava. Their structures and relative configurations were established by extensive spectroscopic analysis. A possible biosynthetic pathway for 1-4 was also proposed.
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Keywords
Psidium guajava
meroterpenoid
guajadial
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Fund:The authors acknowledge the National Basic Research Program of China (973 Program, 2009CB522300), the "West Light" program of Chinese Academy of Sciences, and the National Natural Science Foundation of China (U1132607). |
Issue Date: 11 February 2018
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